Jeff, I'll see if I can clear this up for you -
First, let's take a fairly normal (for studios, anyway) double-framed wall as an example - Let's start with using two layers of 5/8 gypsum on the outer side of each frame, so it looks like the famous "63 dB wall" shown in several places in this forum, including here
http://www.johnlsayers.com/phpBB2/download.php?id=1819
Now, if we break down what's happening in this wall we find that the critical, or coincidence frequency of 5/8 drywall by itself is roughly 2530 hZ; this is the frequency a single drywall panel would resonate at on its own. This is also one of the frequencies that will pass through such a panel easiest, because it's resonant at that frequency.
IF you put more than one such panel on each side of the wall, but don't bond them together, the critical frequency is STILL 2530 hZ, whether you use 1 panel per side or 10. It's only when you BOND more than one panel together continuously, that you create a NEW type of panel with a higher mass, and therefore lower critical frequency. Double the mass and you will halve the frequency.
This means that, by itself, the new, bonded, double-weight panel would have one octave lower resonance than a single panel -
Mass law states that although a double weight SINGLE panel would have higher TL by 6 dB at all frequencies EXCEPT near resonance, it also has one octave lower resonance and so would be weakened (show a dip in isolation) 1 octave lower than a single weight, single panel -
Now, we combine panels and frame and insulation into a complete, double-framed wall - if each side has two NON-glued 5/8 drywall panels, its total mass is double what it would be with only ONE such panel, but its critical frequency is STILL THE SAME as if only one panel were used, IOW it's still 2530 hZ for each side of the wall, even though there are more than one panel on each side.
Now, let's assume we have two 2x4 frames spaced 1 inch apart in this wall - this decides the air gap, which would then = 8 inches, or 200mm. If we place a single, 1-1/4" thick drywall panel on each side of this frame, using standard household fiberglass insulation, prediction software shows that the resulting coincidence/critical frequency occurs at 1265 hZ and causes approximately 8 dB lower TL at that frequency than at surrounding ones - change the panels to two SEPARATE 5/8 drywall panels, which moves the coincidence dip up to 2530, and although you STILL get that 8 dB dip in the TL curve, it happens an octave higher -
This does three things - one, it places the resonance at a higher frequency which isn't as close to the "weighted" center frequency used by the STC curve (500 hZ); two, the higher resonance frequency gets a 6 dB "helping hand" by mass law, since we now have the same mass but TWICE the coincidence frequency, therefore 6 dB better TL, and three - the coincidence frequency is an octave further away from the mass-air-mass resonance of the complete wall structure, so they will have somewhat less interaction (so one loss doesn't exacerbate the other)
I've done a few calculations on this, and if it weren't such a pain in the ass to build, we could get even better results by using 4 layers of 1/4" drywall per side instead of two layers of 1/2", or (even worse) one layer of 1" drywall per side. (This is because 1/4" drywall has an even HIGHER coincidence dip, over 6 kHz - it also assumes NO GLUE.)
I'm about ready to crash, but I hope this helps explain what I meant earlier... Steve