Okay, so here is my SPL graph from today, with no subwoofer, smoothed to 1/24 octave.
There you go!

See all the nasty stuff the smoothing was hiding? You have a big modal dip at just under 96 Hz, and a peak at 148? They were nowhere near as obvious as they are now, and what looked like a single peak at around 60Hz is now clearly a few different things, at 40, 46 and 65 Hz.
You also have a problem with grounding: There are two "tails" in the waterfall plot, at 60 Hz.and 120 Hz. that do not decay over time. They are at a constant level, so they are not acoustic issues. That is "mains hum" getting into your system somewhere. Probably lack of grounding, or a faulty mic cable, or some such. Worth tyring to find and fix that.
Now take a look at the RT60 graph, and you'll see that you have a bass problem in your room. The decay time rises from less than 200 ms for the rest of the spectrum, to over 400 ms below 90 Hz.
Also take a look at the IR graph: You have some pretty large reflections hitting your listening position within 2 ms of the direct sound, so those are most likely coming off your desk or your video screens. To check that, pile up a few thick towels on your desk and repeat the test: I'm betting those will go away, and the mid range will smooth out a bit....
So much more info, just from removing the smoothing!
But you need to calibrate REW properly, using a sound level meter: According to the file you posted, you did those tests at a whopping 140 dB, peaking at 150 dB!

If that really were the level you used, the you would be a red smudge on the floor, and your house would be splinters spread around the neighborhood!

That's the level of sound you normally find inside the tailpipe of a 747 jet engine, at maximum takeoff thrust.... So I think your REW calibration is just a tad off! You should be measuring at about 83 dB for each speaker by itself, or 86 for both together.
You need a sound level meter so you can calibrate REW properly to get those levels right. Right now I can't tell you much about the actual response of the room, since I've never tried to measure one inside a jet engine before...

... even though the graphs are showing the right information, proportionally, it is totally wrong in absolute terms. So I know there's a modal dip at 96 Hz, and I know it is big, but I don't know how big, because the reference point is way off...
So please calibrate REW using a hand held sound level meter, then repeat the measurements. Also, please to one for the left speaker alone, one for the right speaker alone, and one for both together, all in the same file. Label each test right after you do it, so you don't get confused as to which is which.
As long as it can be broken up to make room for the side panels of the desk, I could put one along most of the bottom of the front wall underneath that window and behind the desk.
That would be fine.
I'd have to stop it about a foot from the corner under the window to allow the closet door in the corner to open. If that's all okay, I could make one that would come out about a foot from the wall and go up, I guess, a foot up the wall.
That's fine too. Right now, anything at all will be useful to some extent. It's not going to tame your modes entirely, or course, but it will make some difference.
Front left corner is fine. Front right corner only has (measured it this time) 9" from the corner to the closet opening. Top of the front wall between the window and the left wall is fine
OK. So just do as much as you can get in.
Here is a "nearing construction completion" photo of that wall...
Yup, that's a problem that needs fixing, for sure! Symmetry....
If I can't go up to doubling the price point I was looking at, then the 250W Yorkville would be a much better choice than the 120W Mackie? (hard to say how they measure it, though, because the Yorkville also says 95W under the program power rating, 20W HF Program power and 75W LF program power.... ???!)
I think I'd trust the Mackie rating more than the other one!

Mackie isn't known for exaggerating their specs. They tend to be pretty accurate, and the math works out for their speakers!
It's funny that you mention "underpowered for your room" when my room is so small.
Well, yes, but bass needs a lot more power than mids and highs, simply because it is low frequencies. Are our ears are much more sensitive to mids than lows, so it takes more power to get the same perceived level. Plus, modes, treatment and furniture can all suck out a lot of bass energy from the room, so the speaker needs to be able to put enough energy in to deal with that. There's also the issue of cone size: it simply isn't possible for an 8" or 10" cone to produce low tones as accurately and as smoothly as 15" or 18" cone. Laws of physics, with things like impedance matching and such like.... And it takes a lot more power to move an 18" cone than it does to move a 10" cone, simply because the 18" cone is pushing and pulling on an awful lot more air. So even if both are putting out the same tone at the same level, the 18" jobbie is working harder to do it, and needs more power. And because it has more power, and more surface area, it does a much better job of transferring the energy into the room. Notice that the 12" Yamaha DSS12 has 950 watts power (peak) behind it and it can produce 131 dB, while the 15" Yamaha has 1000 watts of power (peak) yet it only produces 94 dB... Very similar speakers, very similar power, but one is a 15" and the other is only 12"... And other fun things like that... Lots of factors to consider.
But if your budget only extends to the Mackie for now, then that's what I'd go with. It might do the job just fine, and if not then you can always sell it in a few months and upgrade to one of the bigger boys when you have more money. ...
- Stuart -