Is there a general consensus when it comes to bookshelves and DVD / CD shelves as diffusors?
Yes: The general consensus is that they don't work!

You'll only see those "recommendations" from places that don't understand how diffusion actually works (or do understand, but don't care...).
First: real diffuses are tuned. They consist of a series of "wells" that lie below the acoustic "face" of the device. The effective low frequency limit of the diffuser is determined by the maximum
depth of the wells, and the highest frequency is determined by the well
width. The well depth should be 1½ times the wavelength for the desired lowest frequency. The well width should be half of the wavelength for the desired highest frequency. Do the math for a typical book size, or CD case size, and see how well the "diffusion" that you'd get from such a device, lines up with the needs of a typical room...
Second: real diffusers follow carefully arranged mathematical sequences to optimize the diffusion, and ensure that there are no "lobes" in intensity, frequency, or phase. A random arrangement of CD's on a rack will NOT produce a useful diffusion pattern. A lot of research and testing has gone into the mathematical design of diffusers. You might find this book interesting, if you'd like to really understand the subject:
https://www.amazon.com/Acoustic-Absorbe ... 0415471745 It's THE definitive book.
I'm starting to jot down some ideas for the layout of things, inside the control room, and I've always had a lot of books, DVD's and CD's around in my control rooms.
How long is your control room going to be? If it is not long enough, then you cannot successfully use tuned diffusion at all! That same book above will explain why it is a really bad idea to have a diffuser within ten feet (3m) of your head. But here's a more intuitive diagram of why this is a bad idea:
QRD-Diffusion-lobing--pattern-graph-SML-ENH.PNG
That shows the typical lobing pattern created by all tuned diffusers. As you can see, close up to the diffuser there's a huge amount of "chaos" in the diffusion: moving your head a little in that area will give you a very different frequency, timing, and intensity response, so much so that your brain wont be able to accurately determine directionality and frequency response. It's only when you get far away form the device (right at the top of that image above), that the sound field truly becomes "diffuse". According to the theory, that distance is AT LEAST ten feet, for all diffusers, and could be even more, depending on the tuning. If the lowest scattering frequency is very low, then you also need to consider three times the longest wavelength as the critical distance. So it could be more than ten feet, but never less.
However, you do often see small control rooms with large and very expensive tuned diffusers on the rear wall, beautifully made from exotic woods, but just a few feet behind the mix engineer's head.... or even worse, where the client couch is just a few inches in front of a diffuser!

Clearly, some people have a lot more money than they do actual understanding of acoustics...
So, your room would have to be long enough to be able to use diffusion. That implies at least ten feet, plus the distance from the front wall to the mix position, plus the depth of the bass trap behind the diffuser... That implies a MINIMUM room length of about 19 feet. Is yours big enough?
I don't expect the shelves (and the content) to do much in the low end or low mid absorbtion dept. but i can imagine there would be some effectiveness in the mid to high freqency diffusion?
Diffusers don't absorb. Well, they do actually, but only a little, and that's not their purpose. What they do is, they diffuse! (duh!). So what is diffusion? How is it different from absorption? Simple: with absorption, the device physical removes some of the acoustic energy from the room. The sound wave energy is converted into low-grade heat energy by the internal structure of the absorber. So after the wave hits an absorber, it leaves with a lot less energy. And each time it hits, the energy goes down again. That's why small rooms often sound "dead": because there is too much exposed absorption that is sucking the life our of the room.
A diffuser does NOT remove energy from the wave: rather, it scatters and re-directs that energy in multiple different directions, all with the same intensity, frequency, and timing changes. So the TOTAL energy remains the same, but instead of traveling in one single direction like it did when it arrive, it is sent off in many different directions, each one with a much lower energy... but if you add up all those "lower energy" reflections, you still get to the same total energy as the original wave had (with only slight losses). A diffuser spreads the original wave around smoothly, evenly, and consistently... but not up close. Up close, the effect is NOT smooth, even or consistent! You have to be far enough away (ten feet....) before you are in the truly diffuse field. Your brain DOES need that diffuse field to make sense of the room, and feel comfortable in it.... which is why early room design philosophies, such as LEDE, didn't work very well. They were found to be "fatiguing" and "uncomfortable" for long sessions, due to the lack of sufficient diffuse field at the mix position.
So, that's my long lead-in rant to answer your comment: Yes, your randomly placed CDs and books will certainly have "some effectiveness in the mid to high freqency", but the effect would be lousy: it would not be even, not smooth, not consist... at ANY distance. And it would be tuned to the wrong frequency range for your room anyway.
I wonder if I could do a bit of a 'mix and match' when it comes to diffusers, absorbers and bookshelves?
You will undoubtedly need a LOT of absorption! All small rooms do. The smaller it is, the more it needs in the low end. That's a given. It goes without saying. If the room is large enough, then you MIGHT be able to use tuned diffusion, such a Schroeder's, QRD's, PRD's, binary arrays, etc. Otherwise, you'd be restricted to reflection. See this thread :
http://www.johnlsayers.com/phpBB2/viewt ... =2&t=21368 to see how the procedure goes for tuning small control rooms that are too small for numeric-series diffusion. Note: no bookshelves or CD racks!
Not to replace what would be needed for a proper RFZ, per se, but have them co-exist, for aesthetic reasons, at least.
For a true RFZ design, you DO need diffusion! But if the room is not big enough, then it cannot be achieved with numeric-based diffusion. It pretty much has to be purely reflective, or poly-cylindrical based. See the room below...
I can see (in a lot of pictures and designs) that there is quite a bit of real estate towards the front of the control rooms, where 2-3 decent sized absorbers are hung on the walls on either side of the listening position, and then the bare wall in between.
Are you SURE it is bare wall back there?

If so it is not a true RFZ room... What you often see in photos of finished rooms is something that LOOKS like a wall, but really isn't a wall at all.
For example, take a look at this photo (from the most recent post on his thread):
20180502_185258.jpg
See that nice solid back wall there, between the two slotted poly diffusers on each side? That's not a wall! Read the thread, and you'll see that there's several FEET of treatment behind it. And that treatment is doing a lot of the "magic" that I needed to tune the room, as you can see from the graphs.... It's a complicated room to tune, but by careful use of the right things in the right places, it is coming on nicely... (and no bookshelves or CD racks! : )
This, to me, would be an aesthetically interesting place to build some book/cd shelves.
... and each time you take out a book, or re-arrange your CD's, or buy some new ones, or lend some books, the tuning of your room would change...

Probably not a good idea, if you hope to meet the ITU BS.1116-3 spec!
(as opposed to the "four squares, evenly spaced" look.
I don't think you could accuse that room of having a "four squares, evenly spaced" look.!

To me, it looks rather organic, nicely curved, with no even spacing anywhere... it's pseudo-exponential spacing on the slats for the slotted poly, for example.... which is why we are now getting that nice even diffusion that you can clearly see in the last set of graphs I posted there, comparing the "before" and "after" impulse response images...
Any thoughts on something as potentially broad and un-answerable as the "acoustical properties" of a book/cd shelf?
The acoustic properties are known, broadly, but are unpredictable in reality, since every time you move a book, the entire pattern would change. If you really wanted to use this idea, you could take your bookshelf and books to a place like Riverbank Acoustic Labs and have it tested in their highly specialized, world-class testing labs. You could even test a whole series of different book sizes, position, locations, depths, patterns, etc. It might be a bit expensive though: it costs thousands per day to do that, and you'd need many days.
But for a more definitive answer: Take a look at photos of the high-end control rooms from around the world that you see right here on the forum (designed by John and others), or in magazines such as Sound on Sound, Mix, Tape Op, Pro Sound, and others.... How many of the world-class control rooms you see there use bookshelves and CD racks as their acoustic treatment? I think that should answer your question...
One other minor issue: diffusers have to be sealed in order to work effectively... In other words, you'd have to glue all your CDs together, and all your books too, so that there are no air spaces between them, above them, or below them... That might not be much of an option, if you ever wanted to read those books again, or play a CD!
The ONLY place you might perhaps maybe could be try something like that is in a bedroom studio with no budget at all, and where there's no real possibility of getting decent acoustic response out of it. They might provide a tiny bit of benefit, but for the type of pro-level studio you are talking about, that's out of the question.
- Stuart -